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Лаборатория "Металлоорганического катализа" (№ 8)

Зав. лабораторией д.х.н. Нифантьев Илья Эдуардович

 

Краткое описание

Лаборатория «Металлоорганического катализа» была основана в 1963 году академиком Б.А.Долгоплоском. Деятельность сотрудников Лаборатории внесла решающий вклад в разработку советской технологии производства ряда каучуков и в разработку научных основ технологии каталитической 1,4-цис-полимеризации сопряженных диенов.

Основным направлением исследований Лаборатории в наше время является изучение научных принципов создания востребованных органических материалов из нефтехимического и возобновляемого сырья, включая исследование каталитических методов получения и переработки полиолефиновых пластиков, создание природоподобных биоразлагаемых материалов, а также синтез некристаллических олигомеров и полимеров на основе олефинов и диенов. Особое внимание в деятельности Лаборатории уделяется изучению строения материалов методами колебательной спектроскопии, а также DFT-моделированию каталитических процессов, приводящим к искомым материалам и разработка эффективных катализаторов.

Исследования Лаборатории поддерживают РНФ, РФФИ, другие научные Фонды. Лаборатория интенсивно сотрудничает с рядом российских и зарубежных нефтехимических компаний.

Лаборатория приглашает студентов, аспирантов и молодых сотрудников.

 

Наши контакты:

Тел:                +7(985) 727 87 93
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Основные публикации Лаборатории:

2018

Ilya E. Nifant'ev, Pavel V. Ivchenko, Andrey V. Shlyakhtin, Stanislav G. Karchevsky
Mechanistic insights of BHT-Mg catalyzed ethylene phosphate's coordination ring-opening polymerization: DFT modeling and experimental data
Polymers, 10 (2018) 1105
DOI:                             10.3390/polym10101105
IF (WoS):                      2.935
Rank (SJR):                 Q1

I.Nifant'ev, A. Vinogradov, V. Roznyatovsky, Y. Grishin, A. Ivanyuk, I. Sedov, A. Churakov, P. Ivchenko
5,6-Dihydrodibenzo[c,e][1,2] azaphosphinine-based PNP ligands, Cr(0) coordination and Cr (III) precatalysts for ethylene oligomerization
Organometallics, 37 (2018) 2660-2664
DOI:                             10.1021/acs.organomet.8b00427
IF (WoS):                     4.051
Rank (SJR):                 Q1

I.E. Nifant'ev, A. V. Shlyakhtin, V. V. Bagrov, P. D. Komarov,  A. N. Tavtorkin, M. E. Minyaev, M. A. Kosarev and P. V. Ivchenko
Synthesis in aqueous media of poly(ethylene phosphoric acids) by mild thermolysis of homopolymers and block copolymers based on tert-butyl ethylene phosphate
European Polymer Journal, 106 (2018) 249-256
DOI :                            10.1016/j.eurpolymj.2018.07.034
IF (WoS):                      3.741
Rank (SJR):                 Q1

Dmitrii M. Roitershtein, Kseniya I. Minashina, Mikhail E. Minyaev, Ivan V. Ananyev, Konstantin A. Lyssenko, Alexander N. Tavtorkin and Ilya E. Nifant’ev
Flexibility of trans-2-(((2-methoxyphenyl)imino)methyl)phenoxide ligand in rare-earth complexes. Influence of a metal cation radius and a number of the ligands on steric hindrance and ligand coordination modes
Acta Crystallographica Section C: Structural Chemistry, C74 (2018) 1105–1115
DOI:                             10.1107/S2053229618012421
IF (WoS):                      8.678
Rank (SJR):                 Q1

Dmitrii M. Roitershtein, Lada N. Puntus, Alexander A. Vinogradov, Konstantin A. Lyssenko, Mikhail E. Minyaev, Mikhail D. Dobrokhodov, Ilya V. Taidakov, Evgenia A. Varaksina, Andrei V. Churakov, Ilya E. Nifant’ev
Polyphenylcyclopentadienyl ligands as an effective light-harvestig p-bonded antenna for lanthanide +3 ions
Inorg.Chem., 57 (2018) 10199-10213
DOI:                             10.1021/acs.inorgchem.8b01405
IF (WoS):                      4.857
Rank (SJR):                 Q1

Mikhail E. Minyaev, Alexander A. Vinogradov, Andrei V. Churakov, Barbara Kimmich, Ilya E. Nifant'ev and Sandor M. Nagy
Molybdenum complexes for olefin epoxidation with tert-butyl hydroperoxide
Mend. Commun., 28 (2018) 508-510
DOI: DOI:                     10.1107/S2053229618012421
IF (WoS):                     2.098               
Rank (SJR):                 Q2

Ilya E. Nifant'ev, Alexander A. Vinogradov, Alexey A. Vinogradov, Andrey V. Churakov, Pavel V. Ivchenko
Formation of Zr (III) in the reaction of O[SiMe2(η5-C5H4)]2ZrCl2 with LiAlH4  and the selectivity of zirconocene-catalyzed dimerization of α-olefins
Mend. Commun., 28 (2018) 467-469
DOI:                             10.1016/j.mencom.2018.09.004
IF (WoS):                     2.098               
Rank (SJR):                 Q2

John E. Ellis, Mikhail E. Minyaev, Ilya E. Nifant'ev and Andrei V. Churakov
Scandium complexes with the tetraphenylethylene and anthracene dianions
Acta Crystallographica Section C: Structural Chemistry, С74 (2018) 769–781
DOI:                             10.1107/S2053229618007295
IF (WoS):                      8.678
Rank (SJR):                 Q1

Sveta Zhiraslanovna Ozkan, Galina Petrovna Karpacheva, Petr Aleksandrovich Chernavskii, Ella Leont’evna Dzidziguri, Galina Nikolaevna Bondarenko and Galina Viktorovna Pankina
Hybrid Materials Based on Poly-3-amine-7-methylamine-2-methylphenazine and Magnetite Nanoparticles Immobilized on Single-Walled Carbon Nanotubes
Polymers, 10 (2018) 544
DOI:                            10.3390/polym10050544
IF (WoS):                      2.935
Rank (SJR):                 Q1

Mikhail E. Minyaev, Sof’ya A. Korchagina, Alexander N. Tavtorkin, Andrei V.Churakov and Ilya E. Nifant’ev
Dinuclear neodymium and lanthanum bis(2,6-diisopropylphenyl)phosphate complexes bearing hydroxide ligand. Catalytic activity of the Nd complex in 1,3-diene polymerization.
Acta Crystallographica Section C: Structural Chemistry, C74 (2018) 698
DOI:                             10.1107/S2053229618006666
IF (WoS):                      8.678
Rank (SJR):                 Q1

Mikhail E. Minyaev, Alexander N. Tavtorkin, Sof’ya A. Korchagina, Galina N.Bondarenko, Andrei V. Churakov and Ilya E. Nifant’ev
Isomorphous rare-earth tris[bis(2,6-diisopropylphenyl)phosphate] complexes and their catalytic properties in 1,3-diene polymerization and in inhibited oxidation of polydimethylsiloxane.
Acta Crystallographica Section C: Structural Chemistry, C74 (2018) 590
DOI:                             10.1107/S2053229618005570
IF (WoS):                      8.678
Rank (SJR):                 Q1

Ilya E. Nifant'ev, Andrey V. Shlyakhtin, Vladimir V. Bagrov, Pavel. D. Komarov, Alexander N. Tavtorkin, Mikhail E. Minyaev, and Pavel V. Ivchenko
Effective synthetic approach to PGLA materials for biomedical applications
Mend. Commun., 28 (2018) 412-414
DOI :                           10.1016/j.mencom.2018.07.024
IF (WoS):                     2.098   
Rank (SJR):                 Q2

Mikhail E. Minyaev, Ilya E. Nifant'ev, Andrey V. Shlyakhtin, Pavel V. Ivchenko and Konstantin A. Lyssenko
Phenoxide and alkoxide complexes of Mg, Al and Zn and their use for ring-opening polymerization of ε-caprolactone with initiators of different nature
Acta Crystallographica Section C: Structural Chemistry, C74 (2018) 548
DOI:                             10.1107/S2053229618005090
IF (WoS):                     8.678               
Rank (SJR):                 Q1

Ilya E. Nifant'ev, Andrey V. Shlyakhtin, Alexander N. Tavtorkin, Sofia A. Korchagina, Maria S. Chinova, Alexey A. Vinogradov, Alexander A. Vinogradov, Vitaly A. Roznyatovsky, Pavel V. Ivchenko
The synthesis of ultra-high molecular weight poly(1-hexene)s by low-temperature Ziegler-Natta precipitation polymerization in fluorous reaction media
Polymer, 139 (2018), 98-106
DOI:                             10.1016/j.polymer.2018.02.011
IF:                                3.483
Rank (SJR):                 Q1

Bezborodov V.S., Mikhalyonok S.G., Kuz’menok N.M., Arol A.S., Shandryuk G.A., Merekalov A.S., Otmakhova O.A., Bondarenko G.N., Talroze R.V.
Anisotropic derivatives of (-)-L-lactic acid and their nanocomposites
Liquid crystals, 45 (2018) 1223-1233
DOI:                            10.1080/02678292.2018.1427809
IF (WoS):                    2.636
Rank (SJR):                 Q2

Stepan Bazhenov, Alexander Malakhov, Danila Bakhtin, Valery Khotimskiy, Galina Bondarenko, Vladimir Volkov, Mahinder Ramdin, Thijs J.H. Vlugt, Alexey Volkov
CO2 stripping from ionic liquid at elevated pressures in gas-liquid membrane contactor
Journal of Greenhouse Gas Control, 71C (2018) 293-302
DOI:                            10.1016/j.ijggc.2018.03.001
IF (WoS):                     4.078
Rank (SJR):                 Q1 

D.S. Bakhtin, L.A. Kulikov, S.A. Legkov, V.S. Khotimskiy, I.S. Levin, I.L. Borisov, A.L., Maksimov, V.V. Volkov, E.A. Karakhanov, A.V. Volkov
Aging of thin-film composite membranes based on PTMSP loaded with porous aromatic frameworks
Journal of Membrane Science, 554 (2018) 211-220
DOI:                             10.1016/j.memsci.2018.03.001
IF (WoS):                    6.578
Rank (SJR):                 Q1

Ilya E. Nifant'ev, Andrey V. Shlyakhtin, Vladimir V. Bagrov, Pavel. D. Komarov, Maxim A. Kosarev,  Alexander N. Tavtorkin, Mikhail E. Minyaev, Vitaly A. Roznyatovsky and Pavel V. Ivchenko
Synthesis and ring-opening polymerization of glycidyl ethylene phosphate with a formation of linear and branched polyphosphates
Mend. Commun., 28 (2018) 155-157
DOI :                            10.1016/j.mencom.2018.03.015.
IF (WoS):                     2.098
Rank (SJR):                 Q2

Boris Lozhkin, Andrey Shlyakhtin, Vladimir Bagrov, Pavel Ivchenko, Ilya Nifant'ev
Effective stereoselective synthetic approach to substituted 1,4-dioxan-2,5-diones as prospective substrates for ring-opening polymerization
Mend. Commun., 28 (2018) 61-63
DOI:                            10.1016/j.mencom.2018.01.020
IF (WoS):                    2.098   
Rank (SJR):                 Q2

Ilya E. Nifant’ev, Alexander A. Vinogradov, Alexey A. Vinogradov, Igor V. Sedov, Viktor G. Dorokhov,
Anton S. Lyadov, Pavel V. Ivchenko
Structurally uniform 1-hexene, 1-octene, and 1-decene oligomers: Zirconocene/MAO-catalyzed preparation, characterization, and prospects of their use as low-viscosity low-temperature oil base stocks
Applied Catalysis A, General, 549 (2018) 40–50
DOI:                             10.1016/j.apcata.2017.09.016
IF (WoS):                     4.521               
Rank (SJR):                 Q1

2017

I. E. Nifant’ev, A. V. Shlyakhtin, V. V. Bagrov, P. D. Komarov, M. A. Kosarev, A. N. Tavtorkin, M. E. Minyaev, V. A. Roznyatovsky and P. V. Ivchenko
Controlled ring-opening polymerisation of cyclic phosphates, phosphonates and phosphoramidates catalysed by heteroleptic BHT-alkoxy magnesium complexes
Polym. Chem., 8 (2017) 6806–6816
DOI:                             10.1039/c7py01472d
IF (WoS):                     5.375
Rank (SJR):                 Q1

I.E. Nifant'ev, M.E. Minyaev, A.V. Shlyakhtin, P.V. Ivchenko, A.V. Churakov
Bulky ortho-disubstituted phenolates of magnesium, calcium and zinc: structural features and comparison of catalytic properties in ε-caprolactone and rac-lactide polymerization
Mend. Commun., 27 (2017) 341-343
DOI:                             10.1016/j.mencom.2017.07.006
IF (WoS):                    2.098   
Rank (SJR):                 Q2

P.V. Ivchenko, A.V. Shlyakhtin, I.E. Nifant'ev
Ring-opening polymerization of glycolide and rac-lactide, catalyzed by aryloxy magnesium complexes: DFT study of reaction profile and stereocontrol mechanism
Mend. Commun., 27 (2017) 278-280
DOI:                             10.1016/j.mencom.2017.05.020
IF (WoS):                    2.098   
Rank (SJR):                 Q2

Mikhail E. Minyaev, Andrei V. Churakov and Ilya E. Nifant’ev
Structural diversity of polynuclear MgxOy cores in magnesium phenoxide complexes
Acta Crystallographica Section C: Structural Chemistry, C73 (2017) 854–861
DOI:                             10.1107/S2053229617012657
IF (WoS):                      8.678               
Rank (SJR):                 Q1

Minyaev, Mikhail E.; Nifant'ev, Ilya E.; Tavtorkin, Alexander N.; Korchagina, Sof'ya A.; Zeynalova, Shadana Sh.; Ananyev, Ivan V.; Churakov, Andrei V.
Isomorphous rare-earth bis[bis(2,6-diisopropyl-phenyl)phosphate] complexes and their selfassembly into two-dimensional frameworks by intramolecular hydrogen bonds
Acta Crystallographica Section C: Structural Chemistry, C73 (2017) 820-827
DOI:                             10.1107/S2053229617012979
IF (WoS):                      8.678               
Rank (SJR):                 Q1

Nifant'ev, I.E.; Shlyakhtin, A.V.; Bagrov, V.V.; Minyaev, M. E.; Churakov, A. V.; Karchevsky, S.G.; Birin, K. P.; Ivchenko, P. V.
Mono-BHT heteroleptic magnesium complexes: synthesis, molecular structure and catalytic behavior in the ring-opening polymerization of cyclic esters
Dalton Transaction, 46 (2017) 12132-12146
DOI:                             10.1039/c7dt02469j
IF (WoS):                     4.029
Rank (SJR):                 Q1

I.E. Nifant'ev, A.A. Vinogradov, A.A. Vinogradov, S.I. Bezzubov, P.V. Ivchenko.
Catalytic oligomerization of a-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene 'dimer'.
Mendeleev Commun., 27 (2017) 35-37
DOI:                             10.1016/j.mencom.2017.01.010
IF (WoS):                    2.098   
Rank (SJR):                 Q2

Ilya E. Nifant'ev, Pavel V. Ivchenko, Alexander N. Tavtorkin, Alexey V. Vinogradov, Alexander V. Vinogradov
Non-traditional Ziegler-Natta catalysis in a-olefin transformations: reaction mechanisms and product design
Pure and Applied Chemistry, 89 (2017) 1017-1032
DOI:                             10.1515/pac-2016-1131
IF (WoS):                     5.294
Rank (SJR):                 Q1

I. E. Nifant'ev, M. E. Minyaev, A. N. Tavtorkin, A. A. Vinogradov and P. V. Ivchenko
Branched alkylphosphinic and disubstituted phosphinic and phosphonic acids: effective synthesis based on a-olefin dimers and applications in lanthanide extraction and separation
RSC Adv., 7 (2017) 24122–24128
DOI:                             10.1039/c7ra03770h
IF (WoS):                     3.108
Rank (SJR):                 Q1

Dmitrii M. Roitershtein, Lada N. Puntus, Konstantin A. Lyssenko, Ilya V. Taidakov, Evgenia A. Varaksina, Mikhail E. Minyaev, Victor A. Gerasin, Maria A. Guseva, Alexey A. Vinogradov, Maria S. Savchenko and Ilya E. Nifant’ev
An efficient route for design of luminescent composite materials based on polyethylene containing europium dibenzoylmethanate
New J. Chem., 41 (2017) 13663-13672
DOI:                             10.1039/c7nj03055j
IF (WoS):                     3.207
Rank (SJR):                 Q1

2016

I.E. Nifant'ev, A.V. Shlyakhtin, A.N. Tavtorkin, P.V. Ivchenko, R.S. Borisov, A.V. Churakov
Monomeric and dimeric magnesium mono-BHT complexes as effective ROP catalysts
Catalysis Communications, 87 (2016) 106-111.
DOI:                             10.1016/j.catcom.2016.09.018
IF (WoS):                     3.463
Rank (SJR):                 Q1

Nifant'ev Ilya E., Vinogradov Alexey A., Vinogradov Alexander A., Ivchenko Pavel V. Zirconocene-catalyzed dimerization of 1-hexene: Two-stage activation and structure–catalytic performance relationship,
Catalysis Communications, 79 (2016) 6-10
DOI:                             10.1016/j.catcom.2016.02.013
IF (WoS):                     3.463
Rank (SJR):                 Q1

Minyaev Mikhail E., Vinogradov Alexey A., Roitershtein Dmitrii M., Borisov Roman S., Ananyev Ivan V., Churakov Andrei V., Nifant’ev Ilya E.,
Catalytic activity of phenyl substituted cyclopentadienyl neodymium complexes in the ethylene oligomerization process,
Journal of Organometallic Chemistry, 818 (2016) 128-136
DOI:                             10.1016/j.jorganchem.2016.06.003
IF (WoS):                    1.946   
Rank (SJR):                 Q2

Mikhail E. Minyaev, Alexandr A. Vinogradov, Dmitrii M. Roitershtein, Konstantin A. Lyssenko, Ivan V. Ananyev and Ilya E. Nifant’ev
Di- and triphenylacetate complexes of yttrium and europium
Acta Crystallographica Section C: Crystal Structure Communications, C72 (2016) 578–584
DOI:                             10.1107/S2053229616009748
IF (WoS):                      8.678               
Rank (SJR):                 Q1

2015

Minyaev Mikhail E., Roitershtein Dmitrii M., Nifant’ev Ilya E., Ananyev Ivan V., Minyaeva Tatyana V., Mikhaylyev Timofey A.,
A structural study of (1 RS ,2 SR ,3 RS ,4 SR ,5 RS )-2,4-dibenzoyl-1,3,5-triphenylcyclohexan-1-ol chloroform hemisolvate and (1 RS ,2 SR ,3 RS ,4 SR ,5 RS )-2,4-dibenzoyl-1-phenyl-3,5-bis(2-methoxyphenyl)cyclohexan-1-ol.
Acta Crystallographica Section C: Crystal Structure Communications, C71 (2015) 491-498
DOI:                             10.1107/S2053229615009857
IF (WoS):                      8.678               
Rank (SJR):                 Q1

P.V. Ivchenko, I.E. Nifant'ev, O.V. Smetannikov, A.A. Ivanyuk, A.V. Churakov.
Synthetic approach to 6-tert-butyl-5-methoxy-2-methylindenyl zirconium ansa-complexes, bridged in 4-position of indenyl fragment.
Mendeleev Commun., 25 (2015) 435-437.
DOI:                             10.1016/j.mencom.2015.11.012
IF (WoS):                    2.098   
Rank (SJR):                 Q2

Parfenova Lyudmila V., Kovyazin Pavel V., Nifant’ev Ilya E., Khalilov Leonard M., Dzhemilev Usein M.,
Role of Zr,Al Hydride Intermediate Structure and Dynamics in Alkene Hydroalumination with XAlBu i 2 (X = H, Cl, Bu i ), Catalyzed by Zr η 5 Complexes.
Organometallics, 34 (2015) 3559-3570
DOI:                             10.1021/acs.organomet.5b00370
IF (WoS):                     4.051
Rank (SJR):                 Q1

2014

Andrei V. Shlyahtin, Ilya E. Nifant’ev, Vladimir V. Bagrov, Dmitrii A. Lemenovskii, Aleksander N. Tavtorkin and Petr S. Timashev, Synthesis of polyacrylonitrile copolymers as potential carbon fibre precursors in СО2,
Green chemistry, 16 (2014) 1344-1350
DOI:                             10.1039/c3gc41677a
IF (WoS):                     9.01                
Rank (SJR):                 Q1

Ilya E. Nifant’ev, Alexander N. Tavtorkin, Sof’ya A. Korchagina, Inna F. Gavrilenko, Natalya N. Glebova, Natalya N. Kostitsina, Vladimir A. Yakovlev, and Maria P. Filatova, Neodymium tris-aryl phosphates: systematic study of the dependence of catalytic properties in butadiene and isoprene polymerization on the ligand structure,
Applied Catalysis A: General, 478 (2014) 219–227
DOI:                             10.1016/j.apcata.2014.04.007
IF (WoS):                     4.521               
Rank (SJR):                 Q1

 
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